High-Resolution Electron Spectroscopy of Gas-Phase Metal-Aromatic Complexes.
Author | |
Abstract |
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High-resolution electron spectroscopy combines pulsed field ionization zero-electron kinetic energy (ZEKE) detection with in situ laser-assisted synthesis and supersonic expansion. The technique offers sub-meV spectral resolution for the electron spectra of metal complexes and is a powerful tool to study their bonding and structures. This Perspective presents recent progress in single-photon ZEKE spectroscopy of metal-aromatic complexes and focuses on the determination of the electron spin multiplicities, metal binding sites and modes, rotational conformers, and conformational changes of these critical species in organometallic chemistry. |
Year of Publication |
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2011
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Journal |
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The journal of physical chemistry letters
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Volume |
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2
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Issue |
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1
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Number of Pages |
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25-33
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Date Published |
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2011
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URL |
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https://doi.org/10.1021/jz101550d
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DOI |
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10.1021/jz101550d
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Short Title |
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J Phys Chem Lett
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