Partial fluorination overcomes herringbone crystal packing in small polycyclic aromatics.
| Author | |
|---|---|
| Abstract |
:
[structure: see text] We report the synthesis and characterization of partially fluorinated condensed tetracyclic aromatic compounds. Typical edge-to-face/herringbone packing of nonfluorinated analogues is replaced here by columnar stacks with disk planes orthogonal to the columnar axes. Enhanced pi-overlap results with overlaid electron-poor and -rich regions. |
| Year of Publication |
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2005
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| Journal |
:
Organic letters
|
| Volume |
:
7
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| Issue |
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6
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| Number of Pages |
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1067-8
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| Date Published |
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2005
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| ISSN Number |
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1523-7060
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| URL |
:
https://doi.org/10.1021/ol050019c
|
| DOI |
:
10.1021/ol050019c
|
| Short Title |
:
Org Lett
|
| Download citation |
