Catalytic Enantioselective Reaction of 2H-Azirines with Thiols Using Cinchona Alkaloid Sulfonamide Catalysts.
| Author | |
|---|---|
| Abstract |
:
The first catalytic enantioselective reaction of 2H-azirines with thiols has been developed. The obtained aziridines can be converted to optically active oxazolines, aziridylamides, or α-sulfonyl esters. Transformation of these optically active aziridines showed that 2H-azirines act as β,β-dicarbocationic amine synthons. |
| Year of Publication |
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2018
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| Journal |
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Organic letters
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| Date Published |
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2018
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| ISSN Number |
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1523-7060
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| URL |
:
https://dx.doi.org/10.1021/acs.orglett.7b04022
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| DOI |
:
10.1021/acs.orglett.7b04022
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| Short Title |
:
Org Lett
|
| Download citation |
